Soliton-Stripe Patterns in Charged Langmuir Monolayers
نویسندگان
چکیده
We consider a charged Langmuir monolayer problem where electrostatic interaction forces undulations in molecular concentration of the monolayer. Using the Γ-convergence theory in singular perturbative variational calculus, we prove the existence of soliton-stripe lamellar patterns as one-dimensional local minimizers of the free energy, which are characterized by sharp domain walls delineating fully segregated dense liquid and dilute gas regions of the monolayer.
منابع مشابه
Chiral Symmetry Breaking and the Soliton-Stripe Pattern in Langmuir Monolayers and Smectic Films
Chiral symmetry breaking in Langmuir monolayers and smectic films may be modelled by a system of two coupled fields: A scalar field which represents the chirality of the molecules and a vector field which represents the tilt direction of the molecules. In a particular parameter range we prove the existence of a soliton-stripe pattern, using the Γ-limit theory in perturbative variational calculu...
متن کاملTopological manifestations of surface-roughening collapse in Langmuir monolayers.
A transition from surface-roughening collapse to a random network collapse has been investigated in fatty acid Langmuir monolayers. In contrast to the random network crack pattern, the surface-roughening crack pattern grows on a much longer time scale and on a much shorter length scale. A change in the isotherm from a surface pressure "spike" to a "plateau" occurs at the transition. In the surf...
متن کاملDynamics and Melting of Stripes, Crystals, and Bubbles with Quenched Disorder
Two-dimensional systems in which there is a competition between long-range repulsion and short range attraction exhibit a remarkable variety of patterns such as stripes, bubbles, and labyrinths. Such systems include magnetic films, Langmuir monolayers, polymers, gels, water-oil mixtures, and two-dimensional electron systems. In many of these systems quenched disorder from the underlying substra...
متن کاملStripes of partially fluorinated alkyl chains: dipolar Langmuir monolayers.
Stripelike domains of Langmuir monolayers formed by surfactants with partially fluorinated lipid anchors (F-alkyl lipids) are observed at the gas-liquid phase coexistence. The average periodicity of the stripes, measured by fluorescence microscopy, is in the micrometer range, varying between 2 and 8 microm. The observed stripelike patterns are stabilized due to dipole-dipole interactions betwee...
متن کاملA simple model to describe the effect of electrostatic interactions on the composition of mixed self-assembled monolayers.
Due to intermolecular interactions, the surface composition of mixed self-assembled monolayers often differs markedly from the solution composition. In the case of charged surfactants, large deviations from the ideality have been reported. The effect of the electrostatic interactions between charged compounds on the surface composition is examined using a simple gas lattice model, in the Bragg-...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- J. Nonlinear Science
دوره 13 شماره
صفحات -
تاریخ انتشار 2003